Psi4 1.4: Open-source Software for High-throughput Quantum Chemistry

Document Type

Article

Abstract

PSI4 is a free and open-source ab initio electronic structure program providing implementations of Hartree-Fock, density functional theory, many-body perturbation theory, configuration interaction, density cumulant theory, symmetry-adapted perturbation theory, and coupled-cluster theory. Most of the methods are quite efficient, thanks to density fitting and multi-core parallelism. The program is a hybrid of C++ and Python, and calculations may be run with very simple text files or using the Python API, facilitating post-processing and complex workflows; method developers also have access to most of PSI4's core functionalities via Python. Job specification may be passed using The Molecular Sciences Software Institute (MolSSI) QCSCHEMA data format, facilitating interoperability. A rewrite of our top-level computation driver, and concomitant adoption of the MolSSI QCARCHIVE INFRASTRUCTURE project, makes the latest version of PSI4 well suited to distributed computation of large numbers of independent tasks. The project has fostered the development of independent software components that may be reused in other quantum chemistry programs.

Department(s)

Chemistry

Publication Title

Journal of Chemical Physics

Volume

152

Issue

18

Publication Date

5-14-2020

DOI

10.1063/5.0006002

ISSN

00219606

E-ISSN

10897690

PubMed ID

32414239

Comments

The first ten authors and Bethel author, Rollin King, are listed in this record. See full list of authors in the Journal of Chemical Physics. 152, 184108 (2020); https://doi.org/10.1063/5.0006002

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